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Catalytic cleavage of active phosphate and ester substrates by iodoso-and iodoxybenzoates

RA Moss, KW Alwis, JS Shin

文献索引:Moss, Robert A.; Alwis, K. W.; Shin, Jae-Sup Journal of the American Chemical Society, 1984 , vol. 106, # 9 p. 2651 - 2655

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被引用次数: 105

摘要

Abstract: p-Nitrophenyl acetate, p-nitrophenyl hexanoate, and p-nitrophenyl diphenyl phosphate (PNPDPP) were cleaved by o-iodosobenzoate, o-iodoxybenzoate, and 5-(n- octyloxy)-2-iodosobenzoate (3) in aqueous micellar cetyltrimethylammonium chloride solutions at pH 8. The system 3/CTACI was the best catalyst and PNPDPP was the most reactive substrate. In a remarkably rapid hydrolytic reaction at 25 OC, 1.0 XM