European Journal of Inorganic Chemistry

N, N′??Bis (2, 2′??bipyridine??6??ylmethyl)??2, 2′??biphenylenediamines: A Tuneable Ligand Scaffold for Room Temperature Fe2+ SCO Complexes

H Petzold, S Heider

文献索引：Petzold, Holm; Heider, Silvio European Journal of Inorganic Chemistry, 2011 , # 8 p. 1249 - 1254

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被引用次数: 7

摘要

Abstract Condensation and subsequent reduction of 2, 2′-diaminobiphenyls 5 with 6′-and 5′-substituted 6-carbaldehyde-2, 2′-bipyridines 4 yielded N, N′-bis (2, 2′-bipyridine-6- ylmethyl)-2, 2′-biphenyl-enediamines 7, which were employed as hexadendate ligands with N6 donor sets in the synthesis of dicationic [Fe 2+(7-κ 6 N)] complexes 8. Dependent on the substitution pattern the respective complexes are found in the HS state (8b and 8c) or ...