Chiroptical, structural and catalytic properties of S-α-methyl-[1-(substituted phenyl)-2-(2′-pyrido)-1-ethylidene] benzylamines and their Rh (I) and Cu (I) complexes

…, R Kiralj, K Mlinarić-Majerski, V Vinković

文献索引：Sunjic, Vitomir; Sepac, Dragan; Kojic-Prodic, Biserka; Kiralj, Rudolf; Mlinaric-Majerski, Kata; Vinkovic, Vladimir Tetrahedron: Asymmetry, 1993 , vol. 4, # 3 p. 575 - 590

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被引用次数: 5

摘要

Abstract S-α-Methyl-[1-(substituted-phenyl)-2-(2′-pyrido)-1-ethylidene] benzylamines 15– 21 and their Rh (I) complexes 22–28 are prepared and their chiroptical and conformational properties are studied. Free ligands are present as enamines in the solution and in the solid state, but are bound to Rh (I) in the imine form. The CD spectra confirm that complexation of 15–21 induces both structural change and strong conformational perturbations. The ...