Angewandte Chemie International Edition

Polymer??Supported Ionic Liquids: Imidazolium Salts as Catalysts for Nucleophilic Substitution Reactions Including Fluorinations

DW Kim, DY Chi

文献索引：Kim, Dong Wook; Chi, Dae Yoon Angewandte Chemie - International Edition, 2004 , vol. 43, # 4 p. 483 - 485

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被引用次数: 203

摘要

Although nucleophilic substitutions that use metal salts as nucleophiles are crucial synthetic transformations, these reactions, especially fluorinations,[1] often proceed sluggishly because of the limited solubility and low nucleophilicity of metal salts in organic solvents.[2] Phase-transfer catalysts such as crown ethers [3] and quaternary ammonium or phosphonium salts [4] have been used to enhance the solubility and nucleophilicity of the ...