Transfer Hydrogenation of Aryl Ketones with Half??Sandwich RuII Complexes That Contain Chelating Diamines

H Türkmen, İ Kani, B Çetinkaya

文献索引：Tuerkmen, Hayati; Cetinkaya, Bekir; Kani, Ibrahim European Journal of Inorganic Chemistry, 2012 , # 28 p. 4494 - 4499,6

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被引用次数: 10

摘要

Abstract In a comparative study, half-sandwich complexes of Ru II (1) with pyridine-based chelating diamine [NN= 2-aminomethylpiperidine (ampi), a; 2-aminomethylpyridine (ampy), b; 8-aminoquaniline (aquan), c; 4, 4′-dimethyl-2, 2′-bipyridine (dbipy), d; 2, 2′-bipyridine (bipy), e] or amine amide (Ts-ampi, 2a) were synthesized by cleavage of [{(η 6-p-cymene) Ru (μ-Cl) Cl} 2] dimer and the resulting complexes were screened for their efficiency in the ...