Serial synthesis of oxa [3. n] cyclophanes and homooxacalix [n] arenes via reductive coupling of arenedialdehydes, and their X-ray structures

N Komatsu, T Chishiro

文献索引：Komatsu; Chishiro Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 13 p. 1532 - 1537

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摘要

A wide range of oxa [3. n] cyclophanes and homooxacalix [n] arenes is prepared from the corresponding arenedialdehyde via reductive homocoupling reaction in a one-pot fashion. Heterocoupling reaction of arenedialdehyde with bis (trimethylsilyloxymethyl) benzene provides a series of macrocyclic ethers including a new type of oxacalixarene, which consists of the moieties of oxa [3. n] cyclophane and homooxacalix [n] arene; m-or p- ...