Synthesis, characterization, and structural investigations of 1??amino??3??substituted??1, 2, 3??triazolium salts, and a new route to 1??substituted??1, 2, 3??triazoles
G Kaplan, G Drake, K Tollison, L Hall…
文献索引:Kaplan, Greg; Drake, Greg; Tollison, Kerri; Hall, Leslie; Hawkins, Tommy Journal of Heterocyclic Chemistry, 2005 , vol. 42, # 1 p. 19 - 27
Abstract Quarternary salts based upon 3-alkyl substituted 1-amino-1, 2, 3-triazolium cations (alkyl= methyl, ethyl, nypropyl, 2-propenyl, and n-butyl) have been synthesized and characterized by vibrational spectra, multinuclear NMR, elemental analysis, and DSC studies. Subsequent diazotization of these salts results in the exclusive formation of 1-alkyl- 1, 2, 3-triazoles. Single crystal X-ray studies were carried out for 1-amino-3-methyl-1, 2, 3- ...