Rearrangements of 1, 6-dihalotricyclo [4.2. 2.02, 5] decanes. Synthesis of tricyclo [5.3. 0.04, 8] decane derivatives

JR Wiseman, JJ Vanderbilt…

文献索引：Wiseman, John R.; Vanderbilt, Jeffrey J.; Butler, William M. Journal of Organic Chemistry, 1980 , vol. 45, # 4 p. 667 - 671

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被引用次数: 7

摘要

Summary Systematic structure-reactivity data support the pro- posal that the rate-determining transitions states of bro- ... Experimental Section Reagents. The alkynes are commercially available (Chemical Samples), and their purity was verified by GLC and NMR. Acetic acid was purified by refluxing for several hours with chromium trioxide and acetic anhydride and then was distilled through a column.'* Di-tert-butyl peroxyoxalate was kindly provided by Professor T. T. ...