Measurement of the hydride donor abilities of [HM (diphosphine) 2]+ complexes (M= Ni, Pt) by heterolytic activation of hydrogen
…, A Miedaner, WW Ellis, DL DuBois
文献索引：Curtis, Calvin J.; Miedaner, Alex; Ellis, William W.; DuBois, Daniel L. Journal of the American Chemical Society, 2002 , vol. 124, # 9 p. 1918 - 1925
[M (diphosphine) 2] 2+ complexes (where M= Ni and Pt) react with hydrogen in the presence of bases to form the corresponding hydrides,[HM (diphosphine) 2]+. In seven cases, equilibria have been observed from which the hydride donor ability (Δ G° H-) of the hydrides can be calculated. For six of these complexes, the Δ G° H-values calculated using heterolytic activation of hydrogen are compared with those based on thermodynamic cycles using p ...
