Tetrahedron

Generation of Aziridinyllithiums from Sulfinylaziridines with tert-Butyllithium: Properties, Reactivity, and Application to a Synthesis of α, α-Dialkylamino Acid Esters and …

T Satoh, M Ozawa, K Takano, T Chyouma, A Okawa

文献索引：Satoh, Tsuyoshi; Ozawa, Masaki; Takano, Koji; Chyouma, Tosio; Okawa, Akihiro Tetrahedron, 2000 , vol. 56, # 26 p. 4415 - 4425

全文：HTML全文

被引用次数: 36

摘要

Aziridinyllithiums were generated from sulfinylaziridines by a sulfoxide–lithium exchange reaction of sulfoxides with tert-butyllithium at low temperature. The generated aziridinyllithiums were found to be stable in THF at below− 30° C and they are reactive with several electrophiles such as carbonyl compounds, ethyl chloroformate, and phenyl isocyanate. The reactivities of the aziridinyllithiums having several alkyl groups were ...