Facile and Convenient Method of Deuterium Gas Generation Using a Pd/C??Catalyzed H2–D2 Exchange Reaction and Its Application to Synthesis of Deuterium?? …

T Kurita, F Aoki, T Mizumoto, T Maejima…

文献索引：Kurita, Takanori; Aoki, Fumiyo; Mizumoto, Takuto; Maejima, Toshihide; Esaki, Hiroyoshi; Maegawa, Tomohiro; Monguchi, Yasunari; Sajiki, Hironao Chemistry - A European Journal, 2008 , vol. 14, # 11 p. 3371 - 3379

全文：HTML全文

被引用次数: 29

摘要

Abstract The Pd/C-catalyzed H 2–D 2 exchange reaction using a H 2–D 2 O combination provided a general, efficient and environmentally friendly route for the preparation of deuterium gas (D 2). H 2 sealed in a reaction flask was converted into nearly pure D 2, which could be used for the Pd/C-catalyzed one-pot reductive deuteration of various reducible functionalities and the chemoselective one-pot deuterogenation of olefin and ...