International journal of chemical kinetics

Role of phenoxy radicals in PCDD/F formation

S Sidhu, P Edwards

文献索引：Sidhu, Sukh; Edwards, Phil International Journal of Chemical Kinetics, 2002 , vol. 34, # 9 p. 531 - 541

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被引用次数: 24

摘要

Abstract In this work, the role of phenoxy radicals in polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F) formation was investigated by studying the slow oxidation of 2-chlorophenol (2-CP) and 2-chloroanisole (2-CA) at a gas-phase concentration of 4 ppm (∼ 2.1× 10 4 μg/m 3) over a temperature range of 400–800 C. Residence times were maintained at 2.0±0.10 s. PCDD/F reaction products were dibenzofuran, dibenzo-p- ...