Organic letters

Palladium-catalyzed enantioselective conjugate addition of arylboronic acids

F Gini, B Hessen, AJ Minnaard

文献索引：Gini, Francesca; Hessen, Bart; Minnaard, Adriaan J. Organic Letters, 2005 , vol. 7, # 23 p. 5309 - 5312

全文：HTML全文

被引用次数: 116

摘要

The first asymmetric palladium-catalyzed conjugate addition of arylboronic acids to α, β- unsaturated aldehydes, ketones, and esters is described. For cyclic substrates, excellent chemo-, regio-, and enantioselectivities are achieved when a Pd (O2CCF3) 2/DuPHOS catalyst is applied.