Accessible sugars as asymmetric olefin epoxidation organocatalysts: glucosaminide ketones in the synthesis of terminal epoxides
O Boutureira, JF McGouran, RL Stafford…
文献索引：Boutureira, Omar; McGouran, Joanna F.; Stafford, Robert L.; Emmerson, Daniel P. G.; Davis, Benjamin G. Organic and Biomolecular Chemistry, 2009 , vol. 7, # 20 p. 4285 - 4288
A systematically varied series of conformationally restricted ketones, readily prepared from N- acetyl-D-glucosamine, were tested against representative olefins as asymmetric epoxidation catalysts showing useful selectivities against terminal olefins and, in particular, typically difficult 2, 2-disubstituted terminal olefins.
[Emmerson, Daniel P G; Villard, Renaud; Mugnaini, Claudia; Batsanov, Andrei; Howard, Judith A K; Hems, William P; Tooze, Robert P; Davis, Benjamin G Organic and biomolecular chemistry, 2003 , vol. 1, # 21 p. 3826 - 3838]
