Tetrahedron letters

Toward (Z)-selective Horner–Wadsworth–Emmons reaction of aldehydes with 2-fluoro-2-diethylphosphonoacetic acid

S Sano, R Teranishi, Y Nagao

文献索引：Sano, Shigeki; Teranishi, Rie; Nagao, Yoshimitsu Tetrahedron Letters, 2002 , vol. 43, # 50 p. 9183 - 9186

被引用次数: 43

摘要

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The stereoselective Horner–Wadsworth–Emmons reaction of aldehydes with 2-fluoro-2-diethylphosphonoacetic acid utilizing i-PrMgBr afforded (Z)-α-fluoro-α,β-unsaturated carboxylic acids as the major products. ... Ethyl 2-fluoro-2-diethylphosphonoacetate (1) is an efficient fluorinated ...

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