Rare keto-aldoses from enzymatic oxidation: substrates and oxidation products of pyranose 2-oxidase

S Freimund, A Huwig, F Giffhorn…

文献索引：Freimund, Stefan; Huwig, Alexander; Giffhorn, Friedrich; Koepper, Sabine Chemistry - A European Journal, 1998 , vol. 4, # 12 p. 2442 - 2455

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被引用次数: 104

摘要

Abstract: Pyranose oxidases are known to oxidise o-glucose, o-xylose and l-sorbose to keto- aldoses, biochemically interesting compounds that may also be used for synthetic purposes in a variety of reactions. In this study pyranose oxidase from the basidiomycete Penio-phora gigonteo was investigated, and it was found that this enzyme is able to oxidise a broad variety of substrates very effectively. ln analogy to its natural mode of action. most ...