Synthesis of Derivatives of Phenanthrene and Helicene by Improved Procedures of Photocyclization of Stilbenes

HR Talele, MJ Gohil, AV Bedekar

文献索引：Talele, Harish R.; Gohil, Monik J.; Bedekar, Ashutosh V. Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 9 p. 1182 - 1186

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被引用次数: 31

摘要

An improved method has been developed for photocyclization of stilbene to construct phenanthrenes and benzo [c] phenanthrenes. This reaction is promoted by iodine while tetrahydrofuran is used as an efficient and inexpensive scavenger of hydroiodic acid produced during the photocyclization sequence. In another process, cyclohexene is used as a reagent for dehydrogenation step in place of THF–I 2.