Alkyne-containing chelating ligands: synthesis, properties and metal coordination of 1, 2-di (quinolin-8-yl) ethyne

…, M Hysell, JR Goldenberg, AL Rheingold, Y Tor

文献索引：Greco, Nicholas J.; Hysell, Michelle; Goldenberg, Joseph R.; Rheingold, Arnold L.; Tor, Yitzhak Dalton Transactions, 2006 , # 19 p. 2288 - 2290

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被引用次数: 5

摘要

A new alkyne-containing chelating ligand, 1, 2-di (quinolin-8-yl) ethyne, is shown to form a mononuclear 1: 1 complex with silver (I) and chelate the metal ion through both nitrogens and the ethyne moiety as seen by UV and NMR spectroscopy as well as X-ray crystallography.