Novel 10??I??3 Hypervalent Iodine??Based Compounds for Electrophilic Trifluoromethylation

P Eisenberger, S Gischig…

文献索引：Eisenberger, Patrick; Gischig, Sebastian; Togni, Antonio Chemistry - A European Journal, 2006 , vol. 12, # 9 p. 2579 - 2586

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被引用次数: 332

摘要

Abstract The synthesis of a new family of 10-I-3 hypervalent iodine compounds is described in which the CF 3 functionality participates directly in the hypervalent bond. These materials are accessible by nucleophilic ligand substitution at iodine using Me 3 SiCF 3 in the presence of a substoichiometric amount of fluoride. The expected T-shaped geometry at iodine was verified by X-ray crystallographic analyses of three of the products (1- ...