Study on the Effect of the Structure of the Leaving Group in the E1cb Mechanism of Base-Promoted. beta.-Elimination Reactions from N-[2-(p-Nitrophenyl) ethyl] …
S Alunni, P Tijskens
文献索引：Alunni, S.; Tijskens, P. Journal of Organic Chemistry, 1995 , vol. 60, # 26 p. 8371 - 8374
Studies of acid-base catalysis, WD exchange, and solvent isotope effect on the P-elimination reactions with formation of p-nitrostyrene in acetohydroxamate/acetohydroxamic acid buffers at pH 9.05, HzO, p= 1 Mkc1, 25" C, from N-[2-O,-nitrophenyl) ethyllalkylammonium ions with different leaving groups, such as N-methylpyrrolidine 1, N-ethylpyrrolidine 2, N- isopropylpyrrolide 3, N-methylpiperidine 4, N-isopropylpiperidine 5, and N- ...
