Tetrahedron letters

Spectroscopic and chemical evidence for methylene singlet-triplet intersystem crossing in solution

NJ Turro, Y Cha

文献索引：Turro, Nicholas J.; Cha, Yuan Tetrahedron Letters, 1986 , vol. 27, # 51 p. 6149 - 6152

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被引用次数: 2

摘要

Abstract Singlet-triplet intersystem crossing of methylene in perfluorohexane solution has been investigated by CIDNP. Evidence of this process is shown by the polarized absorption 1 H-NMR signal of Cl 3 C CH 2 D, a triplet product, which is obtained upon direct