Dalton Transactions

Iron (II) and zinc (II) monohelical binaphthyl-salen complexes with overlapping benz [a] anthryl sidearms

AV Wiznycia, J Desper, CJ Levy

文献索引：Wiznycia, Alexander V.; Desper, John; Levy, Christopher J. Dalton Transactions, 2007 , # 15 p. 1520 - 1527

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被引用次数: 7

摘要

The synthesis of the polyaromatic aldehyde 1-hydroxybenz [a] anthracene-2- carboxaldehyde is reported via a seven step protocol from 9, 10-dihydroanthracene, with an overall yield of 30%. Two equivalents of the aldehyde are condensed with (R)-1, 1′- binaphthyl-2, 2′-diamine to produce a new binaphthyl-salen ligand, which is subsequently complexed to iron (II) and zinc (II) ions. The ligand and complexes are characterized by ...