Journal of the American Chemical Society

Biosynthesis of pinidine

E Leete, KN Juneau

文献索引：Leete; Juneau Journal of the American Chemical Society, 1969 , vol. 91, # 20 p. 5614 - 5618

全文：HTML全文

被引用次数: 22

摘要

Abstract: The administration of sodium acetate-l-lF to Pinus jeffreyi plants afforded radioactive pinidine (2-methyl-6-(2-trans-propenyl) piperidine). A systematic degradation of the alkaloid indicated that almost all the radioactivity was located on carbon atoms 2, 4, 6, and 9, and was equally distributed between these positions. This result favors the hypothesis that this piperidine alkaloid is derived from a ten-carbon chain formed by the ...