Organic letters

Oxidative hydroxylation mediated by alkoxysulfonium ions

Y Ashikari, T Nokami, J Yoshida

文献索引：Ashikari, Yosuke; Nokami, Toshiki; Yoshida, Jun-Ichi Organic Letters, 2012 , vol. 14, # 3 p. 938 - 941

全文：HTML全文

被引用次数: 30

摘要

Oxidative hydroxylation of toluene derivatives via alkoxysulfonium ion intermediates was achieved by integration of anodic oxidation and hydrolysis to give benzyl alcohols which are also susceptible to oxidation. Alkenes were also oxidized to give 1, 2-diols without overoxidation. The integration of electrochemical oxidative cyclization and hydrolysis was achieved using alkenes bearing a nitrogen atom in an appropriate position to give cyclic β ...