Acid-catalyzed thermal decomposition of 1-aryl-3, 3-dialkyltriazenes in the presence of nucleophiles

N Satyamurthy, JR Barrio, DG Schmidt…

文献索引：Satyamurthy, N.; Barrio, Jorge R.; Schmidt, Derrick G.; Kammerer, Craig; Bida, Gerald T.; Phelps, Michael E. Journal of Organic Chemistry, 1990 , vol. 55, # 15 p. 4560 - 4564

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被引用次数: 36

摘要

The acid-catalyzed thermal decompositions of a number of substituted l-aryl-3, 3- dialkyltriazenes(1) in the presence of nucleophiles have been conducted with a view to understanding the underlying mechanisms of these reactions. These reactions parallel the corresponding diazonium ion reactions in that a heterolytic dediazoniation path competes with a homolytic route. The relative proportion of the products arising due to these two ...