The Journal of Organic Chemistry

Reactivity of primary and secondary N-2-(1, 1-dichloroalkylidene) anilines. V

N De Kimpe, N Schamp

文献索引：De Kimpe,N.; Schamp,N. Journal of Organic Chemistry, 1975 , vol. 40, # 25 p. 3749 - 3756

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被引用次数: 19

摘要

Results As mentioneld in the preliminary comrnunication, l6 reactions of primary N-24 1, l- dichloroalky1idene) anilines 11 with nucleophilic reagents such as sodium methoxide in methanol led tjo both nucleophilic substitution and to Favorskii-type rearrangement. Nucleophilic substitution afforded N-24 1, 1-dimethoxyalkylidene) anilines 13 while the new type of the1 Favorskii rearrangement proceeded stereospecifically with formation of ...