The mechanism of the reaction of (aryloxy) trimethylstannane with methanesulfonyl chloride. Solvent and substituent effects on the rate of the reaction.
S Kozuka, S Yamaguchi, W Tagaki
文献索引：Kozuka; Yamaguchi; Tagaki Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 2 p. 573 - 576
A kinetic study has been conducted on the reactions of (aryloxy) trimethylstannanes with methanesulfonyl chloride giving chlorotrimethylstannane and aryl methanesulfonates. The reaction was found to obey a second order kinetic equation. The solvent effect on the rate of the reaction appeared obscure although a small rate enhancement was observed in a polar solvent. Substituent effect of the aryloxyl group was found to be dependent on the solvent ...
