Synthesis, structural characterization and reactivity of new tin bridged ansa-bis (cyclopentadiene) compounds: X-ray crystal structures of Me 2 Sn (C 5 Me 4 R-1) 2 (R= …
S Gómez-Ruiz, S Prashar, M Fajardo, A Antiñolo…
文献索引：Gomez-Ruiz, Santiago; Prashar, Sanjiv; Fajardo, Mariano; Antinolo, Antonio; Otero, Antonio Journal of Organometallic Chemistry, 2007 , vol. 692, # 14 p. 3057 - 3064
The organo-tin compounds, Me2Sn (C5H4R-1) 2 (R= Me (1), Pri (2), But (3), SiMe3 (4)) and Me2Sn (C5Me4R-1) 2 (R= H (5), SiMe3 (6)), were prepared by the reaction of Me2SnCl2 with the lithium or sodium derivative of the corresponding cyclopentadiene. Compounds 1–6 have been characterized by multinuclear NMR spectroscopy (1H, 13C, 119Sn). In addition the molecular structures of 5 and 6 were determined by single crystal X-ray diffraction ...
