Pentacoordinate silicon compounds. Reactions of silatranes with nucleophiles

G Cerveau, C Chuit, RJP Corriu, NK Nayyar…

文献索引：Cerveau, G.; Chuit, C.; Corriu, R. J. P.; Nayyar, N. K.; Reye, C. Journal of Organometallic Chemistry, 1990 , vol. 389, # 2 p. 159 - 168

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被引用次数: 23

摘要

Abstract The reactions of hydro, organyl and halosilatranes with nucleophiles have been studied. Substitution involving cleavage of equatorial Si O bonds is always observed. Silatranes exhibit reactivity quite different from that of analogous trialkoxysilanes or anionic pentacoordinate silicon compounds.