Helvetica Chimica Acta

Metallbindungsphänomene: Alkoholat??Aggregate als unmittelbare Teilnehmer an Eliminierungsreaktionen

M Schlosser, G Jan, E Byrne, J Sicher

文献索引：Von Schlosser, Manfred; Jan, Gerald; Byrne, Edeline; Sicher, Jiri Helvetica Chimica Acta, 1973 , vol. 56, # 5 p. 1630 - 1637

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被引用次数: 14

摘要

Abstract In solvents of low polarity it is neither a monomolecular nor a dissociated alcoholal species which effects dehydrohalogenation of vic-dihaloalkanes and vic-dihalocycloalkanes but rather a dimeric, trimeric or tetrameric alcoholate aggregate. This behavior has important implications for the stereochemical outcome of such elimination reactions.