Chemical Communications

Ph 2 PI as a reduction/phosphination reagent: providing easy access to phosphine oxides

F Wang, M Qu, F Chen, Q Xu, M Shi

文献索引：Wang, Feijun; Qu, Mingliang; Chen, Feng; Xu, Qin; Shi, Min Chemical Communications, 2012 , vol. 48, # 68 p. 8580 - 8582

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摘要

Compared with the reactivity of Me 3 SiCl, Me 3 SiI has showed special reactivities to promote a variety of useful synthetic transformations. 6 For example, Me 3 SiI can promote the reaction of salicylic aldehydes with carbonyl compounds providing a facile way to construct 4H-benzopyranic scaffold in our previous work. 7 Therefore, we reasoned that Ph 2 PI may also have more special reactivities than Ph 2 PCl, which has been widely used as a phosphine reagent in organic ...