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Small-ring compounds. IX. The reaction of silver cyclobutanecarboxylate with iodine

JD Roberts, HE Simmons Jr

文献索引:Roberts; Simmons Journal of the American Chemical Society, 1951 , vol. 73, p. 5487

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被引用次数: 18

摘要

Discussion Comparison of the physical constants and the infrared absorptions indicates that the substance from the vapor-solid reaction of n-propyl chloride and germanium is principally n-propylgermanium trichloride, and that rearrangement of the propyl groups occurred only to a minor degree during their transfer to germanium. Rearrangement of n- propyl to isopropyl groups has been observed as a result of the pyrolysis of n-propyl ...