Asian Journal of Chemistry

A Rapid and Convenient Synthesis of a-Diketones

S Chen, J Ma, X Zhou, D Liu

文献索引：Chen, Shao-Rui; Ma, Ji-Hai; Zhou, Xue-Qin; Liu, Dong-Zhi Asian Journal of Chemistry, 2011 , vol. 23, # 1 p. 467 - 468

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被引用次数: 1

摘要

Abstract A novel and simple synthetic method for the preparation of series of a-diketones is reported. a-Ditrimethylsiloxyenes were obtained from the readily available materials diacids or diesters through acyloin condensation, which was oxidized to a-diketones using bromine as the oxidation reagent in presence of water. The structures of a-diketones were confirmed by IR, MS, 1H NMR.