Base-induced rearrangements of mesityl thienyl sulfones

WE Truce, B VanGemert, WW Brand

文献索引：Truce,W.E. et al. Journal of Organic Chemistry, 1978 , vol. 43, p. 101 - 105

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被引用次数: 12

摘要

Two mesityl thienyl sulfones (5-mesitylsulfonyl-2-methylthiophene and 2- mesitylsulfonylthiophene) undergo the Truce--Smiles rearrangement. However, the thienyl unit (in contrast to the previously studied naphthyl and suhstitutetl phenyl groups) migrates with a change in orientation regardless of the baseholvent system used. The chemistry of 2- mesitylsulfonylthiophene is complicated by the acidity of the open ct position, with 2 equiv ...