The first example of the copper-free chloro-and hydrodediazoniation of aromatic amines using sodium nitrite, CCl 4, and CHCl 3

KV Kutonova, ME Trusova, PS Postnikov…

文献索引：Kutonova, K. V.; Trusova, M. E.; Postnikov, P. S.; Filimonov, V. D. Russian Chemical Bulletin, 2012 , vol. 61, # 1 p. 206 - 208,3 Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2012 , vol. 1, p. 203 - 205

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被引用次数: 5

摘要

One of the widely used methods for synthesis of chlo roarenes is based on the reaction of aromatic diazonium salts with HCl or other sources of chloride ion in the pres ence of copper salts (Sandmeyer reaction). 1 In spite of considerable success in this type of transformations, this method as a whole does not satisfy modern trends of" green" organic synthesis because of the presence of cop per or its salts, high acidity of the media, and use of low ered ...