The Journal of Organic Chemistry

Deoxygenation of Aromatic o-Dinitroso Derivatives by Phosphines1

JH Boyer, SE Ellzey Jr

文献索引：Boyer,J.H.; Ellzey,S.E. Journal of Organic Chemistry, 1961 , vol. 26, p. 4684 - 4685

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被引用次数: 24

摘要

861 (1921). phines. The present work extends deoxygenation by phosphines to aromatic dtroso derivatives. Triphenylphospbine oxide (11. R= Cab) is obtained in good yield from equimolar quantities of triphenylphosphine and o-dinitrosobenzene in a hydrocarbon solvent. Benzofurazan (I), presumably formed Simultsneously, waa not isolated; however, after StSam distillation of a similar reaction mix-ture in ethanol both products are isolated ...