Journal of the Chemical Society C: Organic

The chemistry of hydroxyquinones. Part II. The autoxidation of 3, 6-dimethylbenzene-1, 2, 4-triol

JF Corbett

文献索引：Corbett,J.F. Journal of the Chemical Society [Section] C: Organic, 1967 , p. 611 - 620

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被引用次数: 7

摘要

A spectroscopic and kinetic study of the autoxidation of 3, 6-dimethylbenzene-1, 2, 4-triol has shown the first stage to proceed by way of a semiquinone intermediate to give the hydroxyquinone, dihydroxybiphenodiquinone, and hydrogen peroxide as the initial products. Subsequent reaction of the hydroxyquinone with alka