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Journal of the American Chemical Society

Structure determination and synthesis of a plant growth inhibitor, 3-acetyl-6-methoxybenzaldehyde, found in the leaves of Encelia farinosa

R Gray, J Bonner

文献索引:Gray; Bonner Journal of the American Chemical Society, 1948 , vol. 70, p. 1249,1250

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被引用次数: 38

摘要

Summary The di-2-cyclohexene-1-y1 ethers of diethylstilbestrol and hexestrol have been prepared by two methods. Application of the Claisen rearrangement to these compounds produced the corresponding 3, 3'-disubstituted derivatives. Use of benzoic anhydride in the rearrangement of the ethers increased the yield considerably.