The Journal of Organic Chemistry

Thermolysis of model compounds for coal. 3. Radical chain decomposition of 1, 3-Diphenylpropane and 1, 4-Diphenylbutane

ML Poutsma, CW Dyer

文献索引：Poutsma, Marvin L.; Dyer, Catherine W. Journal of Organic Chemistry, 1982 , vol. 47, # 25 p. 4903 - 4914

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被引用次数: 60

摘要

Cracking of l, &diphenylpropane (1) at 345-425 OC to give toluene and styrene proceeded much more rapidly than expected from the strength of ita weakest CC bond. Styrene was rapidly consumed in secondary reactions, one of which was addition to 1 to form 1, 3, 5- triphenylpentane. The kinetic order at low conversion over a lo3 variation in initial concentration from neat liquid through solutions in biphenyl to gas at 20 kPa was 1.59 f ...