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A Proof of Structure for 2-Bromo-3-methyl-4-carbethoxypyrrole1

GG Kleinspehn, AH Corwin

文献索引:Kleinspehn; Corwin Journal of the American Chemical Society, 1953 , vol. 75, p. 5295,5297

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被引用次数: 8

摘要

The scheme described for structural proof established that monobrominated 3-methyl-4- carbethoxypyrrole is predominantly 2-bromo-3-methyl-4-carbethoxypyrrole. This is indicated by the fact that iodination leads to a bromoiodopyrrole which is identical with the 2-bromo-3- methyl-4-carbethoxy-5-iodopyrrole obtained from 2-bromo-3-methyl-4-carbethoxy-d- carbomethoxypyrrole. The isomeric bromoiodopyrrole, 2-iodo-3-methyl-4-carbethoxy-5- ...