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Journal of the American Chemical Society

α, β-Unsaturated Aminoketones. III. α-and β-Morpholinobenzalacetones

NH Cromwell

文献索引:Cromwell Journal of the American Chemical Society, 1940 , vol. 62, p. 3470

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被引用次数: 9

摘要

Under special conditions a-bromobenzalacetone reacted with morpholine to give a-bromo- cumorpholinobenzylacetone 111. Com- CsH6CH-cH-cOC6Ha pound I11 reacted slowly with morpholine to give mainly I and traces of II. When I11 was treated with sodium ethoxide a good yield of the light yellow compound I1 resulted. Compound I1 could not be made to add a second molecule of morpholine to give I.'