Structural, magnetic and optical properties of an Fe III dimer bridged by the meridional planar divergent N, N′-bis (salicyl) hydrazide and its photo-and electro- …
{FeIIICl (DMF) 2} 2 (L) where L is N, N′-bis (salicyl) hydrazide has been synthesized as red crystals and characterized using single-crystal diffraction, infrared and UV-vis spectroscopies, and its magnetic properties studied. The dimeric unit in the structure is formed through the two meridional sets of divergent O, N, O coordinating atoms of the hexacoordinated and quadruply charged ligand. With the presence of the inversion ...