The Journal of Organic Chemistry

Investigation of the metabolism of 3, 4, 9, 10-dibenzpyrene

E ÜNSEREN, LF FIESER

文献索引：Uenseren,E.; Fieser,L.F. Journal of Organic Chemistry, 1962 , vol. 27, p. 1386 - 1389

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被引用次数: 16

摘要

In 3, 4, 9, 10-dibenzpyrene the 5-and 8-positions are identical and thus should both possess high reactivity. In accordance with expectations, we found that the hydrocarbon is oxidized to the 5, 8-quinone I1 by either chromic acid in acetic acid or selenium dioxide in nitrobenzene. The product of reaction with lead tetraacetate was shown to be the 5, 8-diacetoxy derivative VI by the preparation of an identical product by reductive acetylation of the quinone I1 and ...