Synthesis of bis (pyridodipyrimidines) as autorecycling redox catalysts and their remarkable turnover in the oxidation of alcohols

…, H Yamato, K Moriyama, T Nagamatsu

文献索引：Yoneda, Fumio; Tanaka, Kiyoshi; Yamato, Hirotake; Moriyama, Kenji; Nagamatsu, Tomohisa Journal of the American Chemical Society, 1989 , vol. 111, # 20 p. 9199 - 9202

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被引用次数: 12

摘要

Abstract: Bis (pyrid0dipyrimidines)(bis-PP's) as redox catalysts, in which two pyridodipyrimidine moieties are linked with polymethylene chains, have been synthesized by the condensation of bis (6-chloro-5-formyluracil-3-yl) alkanes with 6-alkylaminouracils. These bis-PP's oxidized alcohols more efficiently than monomeric pyridodipyrimidines to give the corresponding carbonyl compounds. Particularly, bis (7-methyl-1 O-(n-octyl) ...