Russian journal of organic chemistry

Amination of Some 1, 3-Dinitrobenzenes with Liquid Ammonia–Potassium Permanganate

B Szpakiewicz, M Grzegozek

文献索引：Szpakiewicz; Grzegozek Russian Journal of Organic Chemistry, 2004 , vol. 40, # 6 p. 829 - 833

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被引用次数: 13

摘要

Abstract 1, 3-Dinitrobenzene and some its 2-and 4-substituted derivatives are dehydroaminated in a solution of potassium permanganate in liquid ammonia to give the corresponding mono-or diamino-1, 3-dinitro-benzenes. Under the same conditions, 4-fluoro- 1, 3-dinitrobenzene is converted into 2, 4-dinitroaniline via replacement of the fluorine atom, while 2, 4-dinitrobenzaldehyde gives rise to 2, 4-dinitrobenzamide.