Addition of Hydrogen Sulfide to Unsaturated Amines

SD Turk, RP Louthan, RL Cobb…

文献索引：Turk,S.D. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 2846 - 2853

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被引用次数: 7

摘要

Thiolation of AT-alkenyl compounds with hydrogen sulfide was investigated as a means of obtaining NCCC-SH structures in connection with the synthesis of potential antiradiation drugs. Irradiating allylamine and hydrogen sulfide gave essentially no thiolation. Heating a mixture of allylamine and hydrogen sulfide, with a free-radical-generating agent, gave a mixture, with Markownikoff addition the predominant reaction. With allylamine ...