Cis-trans isomers of 12-S-6 species--dissociative permutational isomerization of a persulfurane

RS Michalak, JC Martin

文献索引：Michalak, Ronald S.; Martin, J. C. Journal of the American Chemical Society, 1981 , vol. 103, # 1 p. 214 - 215

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被引用次数: 7

摘要

Most, but not all, known compounds of hexacoordinate chalcogens (S, Se, Te) have all-trans geometries. Denney has reported3 the low-temperature syntheses of some thermally unstable tetrafluoropersulfuranes, R2SF4, including a few which were constrained to a cis geometry by a ring~ ystem.~ Cady reported4 the only previous example of a cis- persulfurane, SF4 (0SF5) 2, which was not thus constrained. There are no reported ...