New Journal of Chemistry

Electrochemical reduction of nitrotriazoles in aqueous media as an approach to the synthesis of new green energetic materials

L Wallace, CJ Underwood, AI Day…

文献索引：Wallace, Lynne; Underwood, Christie J.; Day, Anthony I.; Buck, Damian P. New Journal of Chemistry, 2011 , vol. 35, # 12 p. 2894 - 2901

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被引用次数: 6

摘要

The synthesis of new azo and azoxy compoundsvia electrochemical reduction of nitrotriazoles has been investigated in aqueous media, using nitrotriazolone (NTO) and nitrotriazole (NTr) as representative substrates. Reduction of NTO produces mainly solid azoxytriazolone (AZTO), with azotriazolone (azoTO) and aminotriazolone (ATO) as minor products, while 3-hydroxylaminotriazole is the major product formed from NTr. AZTO and ...