Are halocarboranes suitable for substitution reactions? The case for 3-I-1, 2-closo-C2B10H11: Molecular orbital calculations, aryldehalogenation reactions, 11B NMR …

…, JM Oliva, F Teixidor, AJ Welch, GM Rosair

文献索引：Vinas; Barbera; Oliva; Teixidor; Welch; Rosair Inorganic Chemistry, 2001 , vol. 40, # 26 p. 6555 - 6562

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被引用次数: 53

摘要

The synthesis of 3-X-1-Ro-carborane (X= I, Br and R= Me, Ph) derivatives is reported, and aryldehalogenation at the B3 position is reported for the first time. The molecular and crystal structures of 1-phenyl-3-bromo-1, 2-dicarba-closo-dodecaborane and 3-phenyl-1, 2-dicarba- closo-dodecaborane are described.