Journal of the American Chemical Society

Aminolysis Products of 1-Chloro-2-hydroxy-3-butene, 1-Hydroxy-2-chloro-3-butene and 1, 2-Epoxy-3-butene

FF Blicke, JH Biel

文献索引：Blicke; Biel Journal of the American Chemical Society, 1957 , vol. 79, p. 5508,5511

全文：HTML全文

被引用次数: 6

摘要

(I) to react with 94% aqueous diethylamine and obtained l-diethylaniino-2-hydroxy-3- butene(111) in good yield. Compound 111 also was formed in about the same yield by interaction of l-hydroxy-2-chloro-3-butene (IV) with 60% aqueous diethylamine. We believe that the formation of the basic butene I11 from IV, and possibly also from I, was due to the intermediate formation of 1, 2-epoxy-3-butene (II). 3 In separate experiments it was found ...